Photometric and spectroscopic analyses of V0775 Cen, a near contact binary with a period of 16 hours and TW Cru, a contact binary with a period of 9 h, indicate both are triple systems. The V0775 Cen spectra are consistent with catalogue values of F0 IV for the primary component; its mass is 1.6 solar and radius 1.7 solar. The effective temperature of the secondary star indicates it has a spectral type of about K4, and its mass is 0.5 solar, yet with a radius of 1.1 solar, it has evolved well past terminal age main sequence. Episodes of emission in the H Balmer and metal lines of TW Cru confirm the conclusion from previously published photometric studies that it is chromospherically active.